Well-Defined Rhodium-Gallium Catalytic Sites in a Metal-Organic Framework: Promoter-Controlled Selectivity in Alkyne Semi-Hydrogenation to E-Alkenes

Citation

Desai, S. P.; Ye, J.; Zheng, J.; Ferrandon, M. S.; Webber, T. E.; Platero-Prats, A. E.; Duan, J.; Garcia-Holley, P.; Camaioni, D.; Chapman, K. W.; Delferro, M.; Farha, O. K.; Fulton, J. L.; Gagliardi, L.; Lercher, J. A.; Penn, R. L.; Stein, A.; Lu, C. C.* J. Am. Chem. Soc. 2018, 140, 15309-15318. 

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RhGa complex in MOF
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48
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RhGa complex in MOF